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Study of tricritical point in triglycineselenate crystal by dynamical heat method at high pressure

В.A. Strukov, Pоlandоv I.N., V.A.Chernenko, V.K. Novik

Moscow University Physics Bulletin 1981. 36. N 3. P. 71

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Annotation

The temperature dependences of the heat capacity of triglycineselenate crystal are experimentally studied over a broad range of temperatures and in direct proximity to the phase transition at different pressures up to 6.5 kbar. The dependences $(∆C)^{-2}=f(T)$ are approximated by straight lines only in the range $T_{c}$-T=0,2—1,5°С. The coefficient В in the Landau expansion of free energy is independent of pressure. Processing of the results in terms of critical indices showed there was a gradual variation in the index with pressure. At a pressure of 4 kbar, it was close to one half. The results are discussed under the assumption that defects influence the phase transition in triglycineselenate. It is concluded that at p = 1 bar, the phase transition in triglycineselenate is a phase transition of the first kind close to the tricritical point.

Authors
В.A. Strukov, Pоlandоv I.N., V.A.Chernenko, V.K. Novik
Moscow State University, Leninskie Gory, Moscow, 119992, Russia
Issue 3, 1981

Moscow University Physics Bulletin

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