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High-overtone spectroscopy of quasilocal CH vibrations in polyatomic molecules: allowance for vibrational-rotational transitions

O. Stengel, N.I. Koroteev

Moscow University Physics Bulletin 1985. 40. N 2. P. 77

  • Article
Annotation

A calculation has been performed on the absorption spectrum in the region of the second overtone of the CH vibration in $(CF_3)_3СН$ and on the fifth overtone of the CH vibration in $CHCl_2F$, where allowance is made for the inhomogeneous rotational broadening. Comparison with the observed spectrum provices the homogeneous contribution to the total spectrum width, which is 20 $cm^{-1}$ for both spectra.

Authors
O. Stengel, N.I. Koroteev
Department of General Physics and Wave Processes, Faculty of Physics, Moscow State University, Leninskie Gory, Moscow, 119992, Russia
Issue 2, 1985

Moscow University Physics Bulletin

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