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The influence of light on the properties of paramagnetic centers in TiO$^2$ nanocrystals doped with nitrogen

N.T. Le$^1$, S.A. Sokolov$^1$, E.A. Konstantinova$^{1,2}$, P.K. Kashkarov$^{1,2}$

Moscow University Physics Bulletin 2013. 68. N 1. P. 61

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Annotation

Samples of nitrogen-doped nanocrystalline titanium dioxide were studied by electron-paramagnetic resonance technique. It was found that the doping of a material with an admixture of nitrogen leads to the appearance of nitrogen-containing paramagnetic centers, viz., N⊙ and NO⊙ radicals. The recharge effect of these centers was observed during illumination. These results may be useful for the development of photocatalytic filters based on doped nanocrystalline titanium dioxide.

Received: 2012 October 23
Approved: 2013 March 6
PACS:
76.30.-v Electron paramagnetic resonance and relaxation
76.30.Fc Iron group
Authors
N.T. Le$^1$, S.A. Sokolov$^1$, E.A. Konstantinova$^{1,2}$, P.K. Kashkarov$^{1,2}$
$^1$Faculty of Physics, Moscow State University, Moscow, 119991, Russia
$^2$Russian Research Center, Kurchatov Institute, Moscow, 123182, Russia
Issue 1, 2013

Moscow University Physics Bulletin

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