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IR spectroscopy of conformational transitions in 1,2-dichloroethane and 1,1.2,2-tetrabro-ethane molecules infiltrated into nanoporous glasses

Yu. V. Starokurov, A. V. Bykov, A. M. Saletsky

Moscow University Physics Bulletin 2020. N 1.

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Annotation

The results of studying the IR absorption spectra under the condition of impaired total internal reflection of 1,2-dichloroethane and 1,1,2,2-tetrabromoethane in porous glasses with different pore radii are presented. The changes in the intensities of the trans and gauche conformations in the studied systems were determined for different pore radii of glass R. The dependences of the differences of the free energies of trans and gauche conformations for 1,2-dichloroethane and 1,1,2,2-tetrabromoethane on the pore radius of porous glass were obtained. At R > 3.5 nm, an increase in the number of g-conformers is observed for 1,2-dichloroethane, while an increase in the number of t-conformers is observed for1,1,2,2-tetrabromoethane . Keywords: IR spectra, porous glasses, trans-, gauche conformation, 1,2 - dichloroethane, 1,1,2,2, -tetrabromoethane, free energy of conformation.

Received: 2019 June 10
Approved: 2020 June 1
PACS:
78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures
Rissian citation:
Ю. В. Старокуров, А. В. Быков, А. М. Салецкий.
ИК спектроскопия конформационных переходов в молекулах 1,2 –дихлорэтана и 1,1.2,2 -тетрабромэтана, инфильтрованных в нанопористые стекла.
Вестн. Моск. ун-та. Сер. 3. Физ. Астрон. 2020. № 1. С. 48.
Authors
Yu. V. Starokurov, A. V. Bykov, A. M. Saletsky
$^1$Faculty of Physics, Moscow State University. M.V. Lomonosov Moscow
$^2$Faculty of Physics, Moscow State University. M.V. Lomonosov Moscow
$^3$Faculty of Physics, Moscow State University. M.V. Lomonosov Moscow
Issue 1, 2020

Moscow University Physics Bulletin

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