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On the influence of fluctuations of close environment of molecules in solvents on theirs absorption spectra

B.D. Rуzhikоv, P.K. Senatоrоv

Moscow University Physics Bulletin 1981. 36. N 5. P. 82

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Annotation

A method for making allowance for the inhomogeneit1es of the close environment of solute molecules on their absorption spectra is suggested. The total molecular energy is written in form of a sum of' the molecule's internal energy and the potential energy of interaction with the close environment. It is assumed that fluctuations of the second component obey a normal distribution, whereas those of the first can take only positive values. Results of using this method for reconstructing the absorption spectrum by rhodamine 6G molecules are presented.

Authors
B.D. Rуzhikоv, P.K. Senatоrоv
Faculty of Physics, Moscow State University, Leninskie Gory, Moscow, 119992, Russia
Issue 5, 1981

Moscow University Physics Bulletin

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