Annotation
A M$\stackrel{..}{o}$ssbauer study of Na$_2$O-CaO-SiO$_2$ glasses with low (up to 1%) content of iron enriched in the $^{57}$Fe isotope has been conducted. The structural and valence states of the Fe$^{2+}$ and Fe$^{3+}$ ions have been analyzed. A component with a characteristic magneto-relaxation shape observed in the spectra is indicative of the formation of ultrasmall Fe$^{3+}$ oxide clusters in glasses.
© 2016 Publisher M.V.Lomonosov Moscow State University
Authors
A.A. Novakova, T.Yu. Kiseleva, I.V. Kovaleva
Department of Solid-State Physics, Faculty of Physics, Moscow State University, Leninskie Gory, Moscow, 119992, Russia
Department of Solid-State Physics, Faculty of Physics, Moscow State University, Leninskie Gory, Moscow, 119992, Russia