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Possibility of laser asymmetric synthesis of hydrogen peroxide molecule enantiomers from a racemic mixture without preliminary molecular orientation

Yu.V. Vladimirova$^1$, B.A. Grishanin$^1$, D.V Zhdanov$^1$, V.N. Zadkov$^1$, H. Takahashi$^2$

Moscow University Physics Bulletin 2005. 60. N 6. P. 47

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Annotation

Using hydrogen peroxide as an example, the specific features of the laser control of the chiral state of an initially racemic mixture of molecules without their preliminary orientation have been studied. The determining role of molecular rotations and the molecular ensemble temperature have been revealed, and promising schemes for the laser asymmetric synthesis of enantiomers from a racemic mixture have been proposed.

Rissian citation:
Ю.В. Владимирова, Б.А. Гришанин, Д.В Жданов, В.Н. Задков, Х. Такахаши.
Возможность лазерного асимметричного синтеза энантиомеров молекул перекиси водорода из рацемической смеси без их предварительной ориентации.
Вестн. Моск. ун-та. Сер. 3. Физ. Астрон. 2005. № 6. С. 37.
Authors
Yu.V. Vladimirova$^1$, B.A. Grishanin$^1$, D.V Zhdanov$^1$, V.N. Zadkov$^1$, H. Takahashi$^2$
$^1$Department of General Physics and Wave Processes, Faculty of Physics, Moscow State University, Leninskie Gory, Moscow, 119992, Russia
$^2$Faculty of Chemistry, Waseda University, Tokyo 169-8555, Japan
Issue 6, 2005

Moscow University Physics Bulletin

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