Annotation
The energy levels of the valence electrons of free ions with completely filled electron shells are analyzed. A linear correlation between term energies $E_{nl}$ and quantum defects $dn_{nl}$ is assumed to exist at constant values of orbital quantum numbers and ion charges for the Li, Na, Cu, Ag, and Au rows. The empirical dependence of quantum defects $dn_{nl}$ on the principle quantum number $n$ is found. It can be used to estimate unknown term energies. It is also demonstrated that the linear dependences of the smooth nonlocal model pseudopotential parameter $A_{nl}$ of free ions on the term energy $E_{nl}$ is the result of their linear dependences on quantum defects $dn_{nl}$.
Received: 2009 October 20
Approved: 2010 May 28
PACS:
31.15.Bs Statistical model calculations
71.15.Dx Computational methodology
71.15.Dx Computational methodology
© 2016 Publisher M.V.Lomonosov Moscow State University
Authors
O.V. Krisko$^1$, V.M. Silonov$^2$, T.V. Skorobogatova$^3$, M.V. Suntsova$^2$
$^1$Faculty of Applied Mathematics and Physics, Vladimir State University, Vladimir, 600005, Russia
$^2$Faculty of Physics, Moscow State University, Moscow, 119991, Russia
$^3$Faculty of Science, Kigali Institute of Science and Technology, Kigali, 3900, Rwanda
$^1$Faculty of Applied Mathematics and Physics, Vladimir State University, Vladimir, 600005, Russia
$^2$Faculty of Physics, Moscow State University, Moscow, 119991, Russia
$^3$Faculty of Science, Kigali Institute of Science and Technology, Kigali, 3900, Rwanda