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Factors affecting the electron state of the exchange forms of iron adsorbed in layered alumosilicates

Factors affecting the electron state of the exchange forms of iron adsorbed in layered alumosilicates

A.A. Zalutskii, R.N. Kuz'min

Moscow University Physics Bulletin 1990. 45. N 2. P. 74

The surface of layered alumosilicates catalyzes the process of iron aggregation. At the first stage, the clay minerals adsorb $Fe^{3+}$ ions from the solution. Subsequently, under the influence of the surface subjected to various external factors, these ions aggregate into $[Fe_2^{3+}(OH)_2^-]^{4+}$ dimers and, at the next stage, they form polymeric films with a hydroxide-like structure. Under low pressures ($\sim10^7 Pa$) and under of influence of direct current, the ions and the dimers undergo the transition $Fe^{3+}\to Fe^{2+}$.

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Application of the Kramers-Kronig transformation in solid state physics

Application of the Kramers-Kronig transformation in solid state physics

A.N. Vasiliev, A.V. Kozlov, V.S. Stepanyuk, A.A. Katsnel'son

Moscow University Physics Bulletin 1990. 45. N 2. P. 78

Difficulties encountered in solving problems of solid state physics with the aid of the Kramers-Kronig relations are analyzed. The application of the fast Fourier transform is shown to reduce considerably the computation time. Criteria are derived for the evaluation of the accuracy of the computation results. The major sources of error in the numerical calculations with these relations are analysed.

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A phenomenological model of phase transitions in ferroelectric alums

A phenomenological model of phase transitions in ferroelectric alums

S.V. Pavlov

Moscow University Physics Bulletin 1990. 45. N 2. P. 83

A phenomenological model is proposed to describe phase transitions in ferroelectric alums. It is shown that the anomaly of the dielectric constant in MASD at 145 К is due to a phase transition in the field of spontaneous polarization which takes place as a result of the interaction between collinear dipole subsystems. Some peculiarities in the behavoir of the dielectric constants of alums under the influence of external factors are explained.

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Degradation of metal-silicon dioxide-silicon structures under electron irradiation and injection of hot electrons from silicon into the oxide

Degradation of metal-silicon dioxide-silicon structures under electron irradiation and injection of hot electrons from silicon into the oxide

Yu.N. Kasumov, S.N. Kozlov, A.N. Nevzorov

Moscow University Physics Bulletin 1990. 45. N 2. P. 87

It is shown that the injection of electrons from silicon into the oxide and the irradiation with electrons lead to similar changes in the energy spectra of the surface states and to an increase in the change instability $Si—SiO_2$-metal structure irrespective of the type of conductivity of the silicon substrate. The charge instability that arises is due to generation of mobile ions and slow electron states in the oxide. The character of the energy spectrum of the surface states depends on conditions of electron injection.

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Multifrequency effects in non-autonomous stable oscillators

Multifrequency effects in non-autonomous stable oscillators

I.I. Minakova, B.G. Simeonova

Moscow University Physics Bulletin 1990. 45. N 2. P. 92

Complex controlled spectra of self-sustained oscillations are shown to be producible in stabilized multiresonator oscillators driven by an external harmonic force. The form of the spectra is related to the detuning of the external force frequencies relative to the oscillator's natural frequencies.

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The role of excited nitrogen molecules in the structure of the ozonosphere

The role of excited nitrogen molecules in the structure of the ozonosphere

M.N. Bidnichenko, A.Kh. Khrgian

Moscow University Physics Bulletin 1990. 45. N 2. P. 95

It is shown that the mechanism of nitric oxide (NO) formation in the middle atmosphere involving the excited particles $N(^2D)$ and $N_2(A^3 \Sigma _n +)$ is indeed capable of producing the high NO concentrations actually observed in auroras and a substantial decrease of the mesospheric ozone concentration.

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Selection of efficient refrigerants for magnetic cooling machines operated within wide temperature intervals

Selection of efficient refrigerants for magnetic cooling machines operated within wide temperature intervals

A.M. Tishin

Moscow University Physics Bulletin 1990. 45. N 2. P. 98

The problem of selecting refrigerants for magnetic refrigerators operated within wide temperature intervals has been considered. The criteria proposed allowed the determination of rareearth metals and alloys which are promising refrigerants for magnetic cooling machines operated within the 20-77 К and 77-300 К temperature intervals.

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The use of computer-aided analysis of diffraction patterns for the automatization of structural studies of phase transformations

The use of computer-aided analysis of diffraction patterns for the automatization of structural studies of phase transformations

A.S. Ilyushin, A.G. Khundzhua, A.V. Sorokin, I.V. Pestov

Moscow University Physics Bulletin 1990. 45. N 2. P. 101

A method has been developed for the calculation of diffraction patterns from a single crystal with second-phase precipitates. The method allows the determination of the lattice parameters, the Bravais lattice type, and the orientation relations between the matrix and precipitation phase lattice from the coordinates of reflections on the X-ray diffraction and electron microdiffraction patterns.

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The $\alpha \leftrightarrow \beta$ transformation kinetics in the Pd-H system at low densities of saturation current

The $\alpha \leftrightarrow \beta$ transformation kinetics in the Pd-H system at low densities of saturation current

G.P. Revkevich, M.A. Knyazeva, A.A. Katsnel'son, G. Fernandez, J. Noas

Moscow University Physics Bulletin 1990. 45. N 2. P. 104

X-ray diffraction methods have been used to study the $\beta$-phase content as a function of the time of palladium saturation with hydrogen. The $\beta$-phase content growth rates are different in regions with different crystallographic orientations. An increase in the saturation time can stabilize the $\beta$-phase.

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Neutrino-antineutrino pair photoproduction on electron (with consideration for the neutrino electromagnetic properties) and its astrophisical aspects

Neutrino-antineutrino pair photoproduction on electron (with consideration for the neutrino electromagnetic properties) and its astrophisical aspects

B.K. Kerimov, S.M. Zeinalov

Moscow University Physics Bulletin 1990. 45. N 1. P. 4

The photoneutrino process, $\gamma _{L,R} e^-_{L,R}\to e^- \nu \bar{\nu}$ due to interactions of the neutrino electromagnetic dipole moments ($\mu_{\nu}, d_{\nu}$) with an electron is examined. Expressions have been obtained for the total cross section of the process and for the photoneutrino luminosity of the Fermi electron gas.

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